2018년 9월 30일 일요일

레포트 clock reaction 화학실험 레포트

레포트 clock reaction 화학실험 레포트
[레포트] clock reaction 화학실험 레포트.hwp


본문
Result (Analyzed Data)
Reaction Mixture
Spend Time until change of color (s)
I-
S2O82-
Relative rate of reaction
1
70
0.08 M
0.04 M
1.43
2
140
0.04 M
0.04 M
0.71
3
116
0.08 M
0.02 M
0.86
Reaction
Reaction flask(100mL)
Reaction flask(50mL)
1
10.0 ml 0.200M KI
10.0 ml 0.100M (NH4)2S2O8
2
5.0 ml 0.200M KI
5.0 ml 0.200M KCl
10.0 ml 0.100M (NH4)2S2O8
3
10.0 ml 0.200M KI
5.0 ml 0.100M (NH4)2S2O8
5.0 ml 0.100M (NH4)2SO4
※ Calculation of I-
Reaction 1
10.0 ml × 0.200 M = 25.0 ml × n1 M
n1 = ( 10.0 ml × 0.200 M ) / 25.0 ml
= 0.08 M
Reaction 2
5.0 ml × 0.200 M = 25.0 ml × n2 M
n2 = ( 5.0 ml × 0.200 M ) / 25.0 ml
= 0.04 M
Reaction 3
10.0 ml × 0.200 M = 25.0 ml × n1 M
n1 = ( 10.0 ml × 0.200 M ) / 25.0 ml
= 0.08 M
※ Calculation of S2O82-
Reaction 1
10.0 ml : 0.100 M = 25.0 ml : n'1 M
n'1 = ( 10.0 ml × 0.100 M ) / 25.0 ml
= 0.04 M
Reaction 2
10.0 ml : 0.100 M = 25.0 ml : n'2 M
n'2 = ( 10.0 ml × 0.100 M ) / 25.0 ml
= 0.04 M
Reaction 3
5.0 ml : 0.100 M = 25.0 ml : n'3 M
n'3 = ( 5.0 ml × 0.100 M ) / 25.0 ml
= 0.02 M
※ Relative rate of reaction (100/t, t : spend time until change of color)
- Rate of reaction 1 : 100 / 70 ≒ 1.43
Rate of reaction 2 : 100 / 140 ≒ 0.71
Rate of reaction 3 : 100 / 116 ≒ 0.86
※ Temperature of reaction mixture : 20.0 ℃
※ Order of reaction
rate = k I-m S2O82- n
Use result of experiment 1, 2
Rate of reaction 1 : 1.43 = k 0.08 m 0.04 n
Rate of reaction 2 : 0.71 = k 0.04 m 0.04 n
Rate`of`reaction`1 over Rate`of`reaction`2 `=` 1.43 over 0.71 `=`2 ^ m `=`2.01 , m`=` log`2.01 over log`2 ` image `1.01
∴ m = 1.01
Rate of reaction 1 : 1.43 = k 0.08 m 0.04 n
Rate of reaction 3 : 0.86 = k 0.08 m 0.02 n
Rate`of`reaction`1 over Rate`of`reaction`3 `=` 1.43 over 0.86 `=`2 ^ n `=`1.66 , n`=` log`1.66 over log`2 ` image `0.73
∴ n = 0.73
Order of reaction : m = 1.01 / n = 0.73
※ Rate constant
rate = k I-m S2O82- n
k = Relative rate of reaction / I-m S2O82- n
Rate constant of reaction 1, k1 = 1.43 / 0.08 1.01 0.04 0.73 = 192.18
Rate constant of reaction 2, k2 = 0.71 / 0.04 1.01 0.04 0.73 = 192.16
Rate constant of reaction 3, k3 = 0.86 / 0.08 1.01 0.02 0.73 = 191.70
Average of rate constant of reaction, k = ( 192.18 + 192.16 + 191.70 ) / 3
= 192.01
∴ k = 192.01
Discussion
This experiment is measuring time that is elapsed when the color of solution started to change color. But at that moment, the elapsed time during experiment might be depend on who does measure. This experiment is clock reaction which include rate determining steps. In this reaction, there is rate constant K which is unrelated to concentration and related to temperature. We can say value of K depends on temperature. So, K is a function of T. Therefore, to get exact data, we must maintain a constant room temperature. When we did the experiments, but, we did not maintain temperature. I think there was difference of temperature, little bit. It can cause error.

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레포트, 실험, 화학실험

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